Around the time that Mr. & Mrs. Smith was releasing, Brad Pitt and Jennifer Aniston were still very much a married couple. It was also the same year when Jennifer Aniston had to bid farewell to her most iconic character to date, Rachel Green, as Friends had its one last hurrah in 2004. Before Brangelina came into existence we had Brad and Jennifer as America's sweethearts. However, it was a tag that both Pitt and Aniston wanted to run away from.