Drew Barrymore had a heartwarming cast reunion on, airing Tuesday. Barrymore welcomed David Arquette, Molly Shannon and Michael Vartan to her show to reminisce about the beloved 1999 rom-com, and Vartan ended up spilling a hilarious memory from their famous kissing scene. starred Barrymore as Josie, a newspaper reporter who enrolls in high school as part of research for a story.