George Stephanopoulos may be most recognizable for his professional demeanor and sharp suits, but he knows how to let loose from time to time.MORE: George Stephanopoulos lets his hair down during family adventureApart from being a wise-cracking wit during Good Morning America, he’ll usually embrace his more casual side when around wife Ali Wentworth.VIDEO: Ali Wentworth jokes she's divorcing George Stephanopoulos live on GMASuch was the case for a recent special occasion, when the two attended a close friend’s country-themed wedding.George and Ali certainly did themselves up for the occasion, as the latter donned a colorful western-style dress with cowboy boots.MORE: George Stephanopoulos' daughter shares different side to mom Ali Wentworth in hilarious behind-the-scenes clipGeorge wasn’t far behind, opting for a black western shirt that had his initials on them with jeans, cowboy boots, and a matching hat.Fans were definitely surprised and delighted to see a different side of the GMA anchor, which Ali shared more of on her social media.